GRAFTING COPOLYMERIZATION OF SERICINE WITH ACRYLIC MONOMER AND PHYSICOCHEMICAL ANALYSIS
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The process of graft copolymerization of sericin protein isolated from natural silk waste with acrylic acid in the presence of
potassium persulfate initiator has been studied. During the reaction, a new copolymer is formed as a result of covalent binding of
polyacrylate segments to the sericin macrochain. The chemical structure of the resulting product was analyzed by IR, 1H PMR and
13C PMR methods. The analysis shows that changes in the spectra of signals and absorption lines characteristic of the functional
groups of the initial sample and the resulting copolymers indicate the formation of copolymers. In particular, the increase in
carboxyl group signals and the appearance of new bonds indicate that polyacrylate monomers are attached to sericin and have new
functional groups
1. O‘zbekiston Respublikasi Prezidenti farmon va qarorlari. 24-mart 2025-yil.
2. Sina Rahimpura, Hadi Jabbari, Hajar Yusofi, Aryan Fathi, Shiva Mahmudi, Mohammad Javad Jafaryan, Navid Shomali,
Siamak Sandogchian Shotorbani. Regulatory effect of sericin protein in inflammatory pathways; Comprehensive review //
Pathology - research and practice. February 10, 2023, 154369
3. Jia Liu., Lin Shi Yan Deng., Meizhen Zou., Bo Cai., Yu Song., Zheng Wang., Lin Wang // Silk sericin-based materials for
biomedical applications // Biomaterials Volume 287, August 2022, 121638
4. Rémi Bascou., Julie Hardouin., Mohamed Amine Ben Mlouka., Erwann Guénin. // Detailed investigation on new chemical-
free methods for silk sericin extraction. Materials today communications Volume 33, December 2022, 10449
5. Karimov, S. Kh., Rafikov, A. S., Ibragimov, A. T., & Askarov, M. A. (2015). [Article title not specified]. International
Polymer Science and Technology, 42(8), 47–49.
6. Zhou, C.-E., Liu, C., Kan, C.-W., Wu, H., Feng, J., Li, R., Li, Z., Zhang, Q., & Li, H. (Year not specified). Antimicrobial
finishing of cotton fabric using plasma-induced grafting-based N-MA. Fibers and Polymers. 2024, vol.25, no.10, pp. 3741-
3749 (9 pages)
7. Singh, M., Lee, S. C., & Won, K. (2024). Phenolation of lignin by graft copolymerization to enhance its reactivity.
International Journal of Biological Macromolecules, 266(Part 2).
8. Wu, D. D., Cheng, L., Ma, P. M., Hong, P., Li, Y., Li, Z. F., Li, Z., Ban, C. M., Ban, X. F., Gu, Z. B., & Cheng, Z. (2024).
Effect of different initiators on the properties of starch-grafted diacetone acrylamide adhesive. International Journal of
Biological Macromolecules, 280(Part 3).
9. Zhang, W., Hu, X., Jiang, F., Li, Y., Chen, W., & Zhou, T. (2024). Fabrication of pH-sensitive smart dressings based on
bacterial cellulose/acrylic acid graft copolymerization method. Journal of Biomaterial Science – Polymer Edition, 35(18),
2767–2789.
10. Verma, A., Kumar, S., Tiwari, A., Akram, W., Sen, S. K., & Bhardwaj, Y. K. (2024). Surface modification of braid silk fiber
by graft copolymerization with vinylbenzyltrimethylammonium chloride (VBT) and its antibacterial study. Russian Journal
of Applied Chemistry, 97(5), 515–525.
11. Yang, Y., Liu, Y., Zhang, S., Cheng, Z., Yan, Y., Liu, J., Lian, M., & Liu, F. (2024). Development, synthesis, characterization
and adsorption capacity of new superabsorbent polymers obtained from poly(potato starch xanthategraft-acrylamide). e-
Polymers, 24(1).
12. Guo, Y. Y., Yin, J., Chen, W., Xu, H. F., Cheng, T. C., & Liu, C. (2025). Critical roles of small silk fibroin molecules in the
self-assembly and properties of regenerated silk fibroin. International Journal of Biological Macromolecules.
13. Szymanski, R., Sosnowski, S., Scott, A. J., & Penlidis, A. (2026). On determination of reactivity ratios for living/quasi-living
copolymerization with slow initiation. Chemical Engineering Science, 320(Part C), 122577.
14. Aranda, F. L., Nesic, A., Miranda, C., Palacio, D. A., Escobar-Avello, D., Castaño, J., Delgado, N., Moeini, A., & Cabrera-
Barjas, G. (2025). Superabsorbent hydrogel preparation by copolymerization of pine bark maleilated polyflavonoids with
acrylic acid. European Polymer Journal, 239, 114226.
15. Zhang, X., Jin, C., Wang, F., Zhu, Y., Ren, Y., Wang, L., & Qi, H. (2025). Copolymerization mechanism of bismaleimide
and cyanate ester resins: Effect of naphthalene structures. Reactive and Functional Polymers, 214, 106282.
16. González Torres, M. (2025). Current status and applications of gamma radiation-induced graft copolymerized chitosan.
Current Organic Chemistry, 29(3), 165–180.
17. Li, Z., Cai, H., Pizzi, A., Li, X., Zhang, J., Du, G., Lu, Y., & Deng, S. (2025). Graft copolymerization for developing high-
adhesion starch-based wood adhesives for environmentally friendly plywood. International Journal of Biological
Macromolecules, 305(Part 1), 141125. Cao,
18. Zhengjun Shi, Chengxinzhuo Jia, Dawei Wang, Jia Deng, Gaofeng Xu, Chunhua Wu, Mengyao Dong, Zhanhu Guo.
Synthesis and characterization of porous tree gum grafted copolymer derived from Prunus cerasifera gum polysaccharide //
International Journal of Biological Macromolecules Volume 133, 15 July 2019, Pages 964-970
19. С.Х.Каримов, А.С.Рафиков, У.Н.Абдарахмонов, М.А.Аскаров. Параметры прививки акриловых и N-виниловых
мономеров к фиброину натурального шелка // Доклады АН РУз. 2016. - №4. - С. 45-48.
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