SWELLING OF POLYACRYLAMIDE GEL FROM SOLUTIONS OF VARIOUS SALTS
In this work, a polyacrylamide gel with 2% cross-links was synthesized and its swelling properties in NaHCO₃, NaCl and CaCl₂
solutions were studied using the optical micrometry method. The results of the study showed that the swelling degree of the gel
depends on the nature and concentration of the electrolytes. It was found that the swelling degree increases in solutions of sodium
salts, and decreases in solutions of calcium chloride. The results obtained indicate the possibilities of using PAAm gel as a sensor
and sorbent material
1. Shatat R. S., Niazi S. K., Ariffin A. Synthesis and Characterization of Different Molecular Weights Polyacrylamide //IOSR
J. Appl. Chem. – 2017. – Т. 10. С. 67-73.
2. Shatat R. S., Niazi S. K., Batati F. S. A. Synthetic Polyelectrolytes based on polyacrylamide: non-ionic, anionic and cationic
Polyacrylamides and their applications in water and wastewater treatment: literature review //Chem. Sci. Int. J. – 2019. – Т.
25. – С. 1-8.
3. Seabrook S. A., Gilbert R. G. Photo-initiated polymerization of acrylamide in water //Polymer. – 2007. – Т. 48. – №. 16. –
С. 4733-4741.
4. Nguyen T. H. et al. Optimizing the conditions of cationic polyacrylamide inverse emulsion synthesis reaction to obtain high–
molecular–weight polymers //Polymers. – 2022. – Т. 14. – №. 14. – С. 2866.
5. Tang Q. et al. Two-step synthesis of polyacrylamide/polyacrylate interpenetrating network hydrogels and its
swelling/deswelling properties //Journal of materials science. – 2008. – Т. 43. – №. 17. – С. 5884-5890.
6. Bhadani R., Mitra U. K. Synthesis and characterization of polyacrylamide hydrogels //Asian Journal of Research in
Chemistry. – 2014. – Т. 7. – №. 3. – С. 345.
7. Rabiee A., Zeynali M. E., Baharvand H. Synthesis of high molecular weight partially hydrolyzed polyacrylamide and
investigation on its properties //Iranian Polymer Journal. – 2005. – Т. 14. – №. 7. – С. 603.
8. Fu X., Yang Q., Zhang Y. Thermal decomposition behavior and mechanism study of cationic polyacrylamide: X. Fu et al
//Journal of Thermal Analysis and Calorimetry. – 2021. – Т. 146. – №. 3. – С. 1371-1381.
9. Gomes C., Dias R. C. S., Costa M. R. P. F. N. Static light scattering monitoring and kinetic modeling of polyacrylamide
hydrogel synthesis //Processes. – 2019. – Т. 7. – №. 4. – С. 237.
10. Gagarin A.N.; Tokmachev M.G.; Trobov H.T.; Ferapontov N.B. Effect of Ion Hydration on the Degree of Swelling of a
Crosslinked Polyvinyl Alcohol Gel. Russian Journal of Physical Chemistry A 2020, 94 (1), 95–101.
11. Tokmachev M.G., Ferapontov N.B., Gagarin A.N. // Journal of Mathematical Chemistry. 2017. 55, P.142-152.
12. M.G. Tokmachev, N.B. Ferapontov, I.O. Agapov, Kh.T. Trobov, Colloid journal. 2018. 80, P. 96-104.
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