SYNTHESIS AND STUDY OF COMPLEX COMPOUNDS OF URANYL ION WITH 2-AMINO-1-METHYLBENZIMIDAZOLE
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Complex compounds of uranyl ion with 2-amino-1-methylbenzimidazole (MAB) and diethyldithiocarbamate (DEDTK) were synthesized and studied. The composition and structure of the resulting complex compounds were established using scanning electron microscopy with energy dispersive analysis, IR and Raman spectroscopy, and differential thermal analysis. The dependence of the composition, structure and properties of complex compounds on the nature of the complexing agent and methods of ligand coordination has been established.
Холида ЖАББОРОВА, Сардор МУРОДОВ, & Шахло ДАМИНОВА. (2024). SYNTHESIS AND STUDY OF COMPLEX COMPOUNDS OF URANYL ION WITH 2-AMINO-1-METHYLBENZIMIDAZOLE. «ACTA NUUz», 3(3.1), 372–376. https://doi.org/10.69617/nuuz.v3i3.1.1850
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2. Khedr A.M. and Saad F.A. Synthesis, structural characterization, and antimicrobial efficiency of sulfadiazine azo-azomethine dyes and their bi-homonuclear uranyl complexes for chemotherapeutic use // Turkish Journal of Chemistry. -2015. -V.39. -N2. -P. 267–280.
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8. Oldham W.J., Scott B.L., Abney K.D., Smith W.H., Costa D.A. Chloroheptakis (dimethyl sulfoxide) uranium (IV) trichloride // Acta Cryst. C58. -2002. m139–m140.
9. Daminova Sh.Sh., Kadirova Z.Ch., Sharipov X.T. IR spectroscopic study of transition metals with impregnated sorbents based on Porolas // Uzbekistan chem. journal. -2016. -N6. -P.3-9
10. Gordon H.J., Iain M., Mark J.S., Helen M.S., Collison D., Helliwell M. and McKinney J.D. The structural and spectroscopic characterisation of three actinyl complexes with coordinated and uncoordinated perrhenate: [UO2(ReO4)2(TPPO)3], [{(UO2)(TPPO)3}2(_2-O2)][ReO4]2 and [NpO2(TPPO)4][ReO4] // Dalton Trans 2004, 734-740.
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12. Gatto C.C., Lang E.S., Jagst A., Abram U. Dioxouranium(VI) complexes with 2,6-acetylpyridinebenzoylhydrazones and -semicarbazones // Inorganica chimica acta. -2004. -V.357. -P. 4349–4644.
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