FORMATION OF SILICON SURFACE MORPHOLOGY DURING ELECTROCHEMICAL ETCHING
This article provides a detailed description of the technology for obtaining porous silicon layers using the anodic etching method.
During the research, key technological parameters influencing the electrochemical etching process, including the composition of
the HF-acid-based electrolyte, current density, voltage values, and etching duration, were systematically analyzed. Furthermore,
the impact of the silicon wafer's crystalline state on the formation of the porous structure was investigated. As a result of the
conducted experiments, optimal technological regimes were identified, allowing for precise control over critical morphological
indicators such as pore diameter, depth, and layer homogeneity. Based on the findings, necessary technological recommendations
have been developed to stabilize the formation process of porous silicon and to implement this method into industrial production.
1. Zhang, G. X. (2006). Porous silicon: morphology and formation mechanisms. In Modern aspects of electrochemistry (pp.
65–133). https://doi.org/10.1007/978-0-387-31701-4_2
2. Santos, A., & Kumeria, T. (2015). Electrochemical etching methods for producing porous silicon. In Springer series in
materials science (pp. 1–36). https://doi.org/10.1007/978-3-319-20346-1_1
3. Losic, D., & Santos, A. (2015). Electrochemically engineered nanoporous materials. In Springer series in materials
science. https://doi.org/10.1007/978-3-319-20346-1
4. Lytovchenko, V. (2017). Preparation and study of porous Si surfaces obtained using the electrochemical
method. Semiconductor Physics Quantum Electronics & Optoelectronics, 20(4), 385–
395. https://doi.org/10.15407/spqeo20.04.385
5. Smith, R. L., & Collins, S. D. (1992). Porous silicon formation mechanisms. Journal of Applied Physics, 71(8), R1–
R22. https://doi.org/10.1063/1.350839
6. Zhao, M., McCormack, A., & Keswani, M. (2016). The formation mechanism of gradient porous Si in a contactless
electrochemical process. Journal of Materials Chemistry C, 4(19), 4204–4210. https://doi.org/10.1039/c6tc00309e
7. Kumar, P., Lemmens, P., Ghosh, M., Ludwig, F., & Schilling, M. (2009). Effect of HF concentration on physical and
electronic properties of electrochemically formed nanoporous silicon. Journalof Nanomaterials, 2009(1).
8. https://doi.org/10.1155/2009/728957
9. Granitzer, P., Rumpf, K., Pölt, P., Reichmann, A., & Krenn, H. (2006). Self-assembled mesoporous silicon in the crossover
between irregular and regular arrangement applicable for Ni filling. Physica E Low-dimensional Systems and
Nanostructures, 38(1–2), 205–210. https://doi.org/10.1016/j.physe.2006.12.031
10. Kumar, P., & Huber, P. (2007). Effect of etching parameter on pore size and porosity of electrochemically formed nanoporous
silicon. Journal of Nanomaterials, 2007, 1–4. https://doi.org/10.1155/2007/89718
11. Lehmann, V., Stengl, R., & Luigart, A. (2000). On the morphology and the electrochemical formation mechanism of
mesoporous silicon. Materials Science and Engineering B, 69–70, 11–22. https://doi.org/10.1016/s0921-5107(99)00286-x
12. Kim, H., & Cho, N. (2012). Morphological and nanostructural features of porous silicon prepared by electrochemical
etching. Nanoscale Research Letters, 7(1), 408. https://doi.org/10.1186/1556-276x-7-408
13. Khinevich, N., Juodėnas, M., Tamulevičienė, A., Bandarenka, H., & Tamulevičius, S. (2021). Tailoring mesoporous silicon
surface to form a versatile template for nanoparticle deposition. Coatings, 11(6), 699.
14. https://doi.org/10.3390/coatings11060699
15. Klimenko, A., Kashko, I., Bondarenko, V., Astrova, E., Zhdanov, V., Rumyantsev, A. M., Amoros, P., Gomez, M., Cantarero,
A., & Matveeva, E. (2017). Planar Mesoporous Silicon Flakes with Microns Thicknesses As an Anode Material for Li-Ion
Batteries: Fabrication, Characterization and Electrochemical Tests. ECS Meeting Abstracts, MA2017-01(43),
2002. https://doi.org/10.1149/ma2017-01/43/2002
16. Kuntyi, О., Zozulya, G., & Shepida, M. (2022). Porous silicon formation by electrochemical etching. Advances in Materials
Science and Engineering, 2022, 1– https://doi.org/10.1155/2022/1482877
17. Ouyang, H., Christophersen, M., & Fauchet, P. M. (2005). Enhanced control of porous silicon morphology from macropore
to mesopore formation. Physica Status Solidi (A), 202(8), 1396–1401. https://doi.org/10.1002/pssa.200461112
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