STUDY OF MIXED-LIGAND COMPOUNDS OF SOME 3d-METALS WITH LIGANDS BASED ON 2- AMINOBENZIMIDAZOLE AND MONOETHANOLAMINE
The article describes the synthesis of new multi-ligand complex salts of Co(II), Ni(II), Cu(II) and Zn based on 2-
aminobenzimidazole and monoethanolamine and determined their composition, structure and properties using physicochemical
methods such as: scanning electron microscopy and energy dispersive analysis (SEM-EDX), X-ray phase and thermal analysis as
well as IR spectroscopy. It was shown that the metal atom is monodentately coordinated through the nitrogen atom of the
imidazole ring in the 2-aminobenzimidazole molecule and bidentately coordinated through the nitrogen atoms of the amino group
and the oxygen of the hydroxyl group of monoethanolamine
1. Sunil S., Arul G.D.A., Mathan S. Design, Synthesis and Biological Evaluation of 2-Aminobenzimidazole Derivatives as
DPP4 Inhibitors // Current Bioactive Compounds. – 2020. - Vol. 16. - Issue 5. - P.696 – 702.
2. Joseph J., Suman A., Nagashri K., Joseyphus R.S., & Balakrishnan N. Synthesis, characterization and biological studies of
copper(II) complexes with 2-aminobenzimidazole derivatives // Journal of Molecular Structure. - 2017. – Vol.1137. –P.
17–26.
3. Imran M., Shah F.A., Nadeem H., Zeb A., Faheem M., Naz S., Li, S. Synthesis and Biological Evaluation of
Benzimidazole Derivatives as Potential Neuroprotective Agents in an Ethanol-Induced Rodent Model // ACS Chemical
Neuroscience. - 2021. – Vol. 12(3). – P. 489–505.
4. Хубаева Т.О., Хубаева И.В. Синтез, свойства и антиоксидантная активность производных бензимидазола с
фрагментом пространственно-затрудненного фенола // Вестник ВГУ, серия: Химия. Биология. Фармация. - 2014. -
№ 3. - С.42-47.
5. Hussain A., AlAjmi M.F., Rehman M.T., Amir S., Husain F.M., Alsalme A., Khan R.A. Cоpper(II) Cоmplexes as pоtential
anticancer and Nоnsterоidal anti-inflammatоry agents: In vitrо and in vivо studies // Sсientifiс Repоrts. - 2019. - Vоl. 9(1).
- P. 5237-5245.
6. Ricardо G.C., Pasha M.K., Nadav A., Dayоng Zh., Mоtti G., Brоsk B., Gavin M. Dissоvery and characterizatiоn оf 2-
Aminоbenzimidazоle Derivatives as Seleсtive NОD1 Inhibitоrs // Сhemistry & Biоlоgy. - 2021. -Vоl. 18. - P. 825–832.
7. R. Kalarani, M. Sankarganesh, G.G. Vinоth Kumar, M. Kalanithi. Synthesis, spectral, DFT calculatiоn, sensоr,
antimicrоbial and DNA binding studies оf Cо(II), Сu(II) and Zn(II) metal Cоmplexes with 2-aminоbenzimidazоle SShiff
base // Jоurnal оf Mоlecular Struсture. - 2020. - Vоl.1206. - P. 127725-127734.
8. Накамото К. ИК спектры неорганических и координационных соединений. - М.: Мир. - 1996. - 206 с.
9. Топор Н.Д., Огородова Л.П., Мельчакова Л.В. Термический анализ минералов и неорганических соединений.
Москва: Изд-во МГУ, 1987. - С.190.
10. Шаталова Т.Б., Шляхтин О.А., Веряева Е. Методы термического анализа. – Москва: 2011. – 72 с.
11. Кукушкин Ю.Н., Ходжаев О.Ф., Буданов В.Ф., Парпиев Н.А. Термолиз координационных соединений. Ташкент:
Наука, 1986.- 198 с.
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