DEVELOPMENT AND APPLICATION OF A PHOSPHORUS - NITROGEN OLIGOMERIC FLAME RETARDANT FOR CELLULOSE-BASED TEXTILE MATERIALS
This study reports the development of an environmentally friendly and efficient oligomeric flame retardant for cellulose-containing
textile materials. The flame retardant was synthesized using magnesium hydroxide, orthophosphoric acid, urea, and glycerin, and
investigated at three different compositional ratios. Optimal synthesis conditions were determined to be 150 °C for 1.5 h. The
physicochemical properties and flame-retardant performance of the obtained products were systematically evaluated. The results
revealed that the formulation obtained by method 1 exhibited the highest efficiency, increasing the limiting oxygen index of the
treated fabrics up to 29.3%. Chemical interaction between the flame retardant and cellulose hydroxyl groups significantly enhanced
washing durability, providing 8–10 times higher resistance compared to conventional water-soluble flame retardants. The proposed
technology combines high flame resistance, environmental safety, and cost-effectiveness, making it a promising solution for
protective and functional textile applications.
1. Wang X, Song L, Yang H, Xing W, Kandol B, Hu Y. (2012) Simultaneous reduction and surface functionalization of
graphene oxide with POSS for reducing fire hazards in epoxy composites. J. Mater Chem 22:22037–22043
2. Jing J, Zhang Y, Fang ZP, Wang DY (2018) Core-shell flame retardant/graphene oxide hybrid: a self-assembly strategy
towards reducing fire hazard and improving toughness of polylactic acid. Compos Sci Technol 165:161–167
3. Huang G, Song P, Liu L, Han D, Ge C, Li R, Guo Q (2016) Fabrication of multifunctional graphene decorated with bromine
and nano-Sb2O3 towards high-performance poly mer nanocomposites. Carbon 98:689–701
4. Wang X, Zhou S, Xing W, Yu B, Feng X, Song L, Hu Y. (2013) Self-assembly of Ni–Fe layered double hydrox ide/graphene
hybrids for reducing fire hazard in epoxy composites. J Mater Chem A 1:4383–4390
5. Nazokat M., Fayzulla N. Analysis of the thermal stability and surface area of antipyrenes synthesized for textile materials
//Universum: химия и биология. – 2024. – Т. 3. – №. 12 (126). – С. 15-20.
6. Музаффарова Назокат, Нуркулов Файзулла, Джалилов Абдулахат Синтез нового агренита с высоким содержанием
фосфора и азота и его использование в хлопковых тканях // Универсум: техническая наука. 2022. №8-3 (101). URL:
cotton-fabrics
7. Muzaffarova N.S. et al. Modifikatsiyalangan tabiiy to‘qimachilik materiallarning termik barqarorligi //Journal of Chemistry
of Goods and Traditional Medicine. – 2023. – Т. 2. – №. 4. – С. 23-33.
8. 8 Muzaffarova N.S. et al. Synthesis of fire retardant with phosphorus and metal for preservation and reach of reduction of
flammability of textile materials //Kimya Problemleri. – 2024. – Т. 22. – №. 3. – С. 290-302.
9. Muzaffarova, N.Sh., & Nurkulov, F.N. (2022). Study of oligomer-antipyrine synthesis and properties of nitrogen, phosphorus
and zinc storage. ISJ Theoretical & Applied Science, 01 (105), 489-492. https://dx.doi.org/10.15863/TAS
10. Muzaffarova N.SH., Nurqulov F.N, Jalilov A.T Olovbardosh to‘qimachilik materiallari uchun fosfor, azot saqlagan
antipirenlar //NamDU ilmiy axborotnomasi-Nauchniy vestnik NamGU. – 2022. – С. 152-156.
11. Muzaffarova, N., F.Nurkulov, and N.Toshtemirova. "Synergic effect of fire retardants and their analogues for textile
materials." Science and innovation 3.A2 (2024): 5-9.
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