SYNTHESIS OF ECOLOGICAL ADDITIVES BASED ON CHITOSAN AND STYRENE-(METH)ACRYLIC ACID COPOLYMERS FOR IMPROVING LOW-TEMPERATURE PROPERTIES OF BIODIESEL FUEL
This article presents the results of synthesizing ecological additives for biodiesel fuel based on aminopolysaccharide chitosan
derived from Apis Mellifera and styrene-(meth)acrylic acid copolymers. The optimal copolymerization conditions were
established: molar ratio of acrylic (meth)acid to styrene 1:1, temperature 75°C, duration 3 hours. The copolymer yield was 82–
85% and molecular weight 45,000–52,000 g/mol. Adding 0.3% of the synthesized additive to biodiesel fuel lowers the pour point
from -12°C to -28°C and the cold filter plugging point from -6°C to -18°C. The physical-chemical properties of the fuel with the
additive meet the O‘zDTs 989:2010 standard requirements. A resource-saving technology for producing the ecological additive
has been developed and introduced at "Sanoat Energetika Guruhi" LLC.
1. Hoekman S.K., Broch A., Robbins C., Ceniceros E., Natarajan M. Review of biodiesel composition, properties, and
specifications // Renewable and Sustainable Energy Reviews. – 2012. – Vol. 16(1). – P. 143–169.
2. Knothe G. "Designer" Biodiesel: Optimizing Fatty Ester Composition to Improve Fuel Properties // Industrial &
Engineering Chemistry Research. – 2012. – Vol. 51(4). – P. 1698–1708.
3. O‘zbekiston Respublikasi Prezidentining 2022 yil 28 yanvardagi PF-60-son «Yangi O'zbekistonning 2022–2026 yillarga
mo'ljallangan taraqqiyot strategiyasi» to'g'risidagi farmoni. – Toshkent, 2022.
4. Younes I., Rinaudo M. Chitin and Chitosan Preparation from Marine Sources: Structure, Properties and Applications //
Marine Drugs. – 2015. – Vol. 13(3). – P. 1133–1174.
5. Dash M., Chiellini F., Ottenbrite R.M., Chiellini E. Chitosan: A versatile semi-synthetic polymer in biomedical
applications // Progress in Polymer Science. – 2011. – Vol. 36(8). – P. 981–1014.
6. Atadashi I.M., Aroua M.K., Aziz A.A. Biodiesel separation and purification: a review // Renewable Energy. – 2011. – Vol.
36(2). – P. 437–443.
7. Varatharajan K., Cheralathan M. Influence of fuel additives on NOx emissions in biodiesel-fuelled CI engine // Fuel. –
2012. – Vol. 107. – P. 585–592.
8. Islam S., Bhuiyan M.A.R., Islam M.N. Chitin and Chitosan: Structure, Properties and Applications in Biomedical
Engineering // Journal of Polymers and the Environment. – 2017. – Vol. 25(4). – P. 854–866.
9. Kaur S., Dhillon G.S. The versatile biopolymer Chitosan: potential sources, evaluation of extraction methods and
applications // Critical Reviews in Microbiology. – 2014. – Vol. 40(3). – P. 155–175.
10. Turobjonov S.M., Hamidov V.N. Dizel yoqilg'ilari uchun qo'ndirmalar kimyosi. – Toshkent: Fan, 2018. – 215 b.
11. Bashkatova S.T., Vasileva Ye.N., Kotin Ye.B. Issledovanie mexanizma depressornogo deystviya sopolimerov //
Nefteximiya. – 1993. – T.33, №6. – S. 564–571.
12. Ivanov V.I., Xrapov V.S., Shapkina L.N. Sopolimery etilena s alkilmetakrilatami kak depressornye prisadki // Ximiya i
texnologiya topliv i masel. – 1981. – №11. – S. 41–42.
13. Saidov J.E., Urinov U.K., Kamolov X. Rezultaty ispytaniya depressornoy aktivnosti sopolimernyx prisadok // O‘zbekiston
milliy universiteti jurnali. – 2022. – №3. – B. 252–254.
14. Urinov U.K., Muzaffarov F.B., Saidov J.E. va boshqalar. Sintez i izuchenie svoystv novyx polimernyx nanokompozitov //
Kimyo va kimyo texnologiyasi. – 2021. – №20(362). – S. 17–21.
15. Gonciarz W., Balcerczak E. va boshqalar. Chitosan-based formulations for therapeutic applications: A recent overview //
Journal of Biomedical Science. – 2025. – Vol. 32(1). – P. 62.
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