КИНЕТИЧЕСКИЕ ЗАКОНОМЕРНОСТИ ОЛИГОМЕРИЗАЦИИ ПАВ НА ОСНОВЕ 2-БРОММЕТИЛОКСИРАНА С 1,3-ДИФЕНИЛГУАНИДИНОМ
This article presents data on the interaction of 2-bromomethyloxirane with 1,3-diphenylguanidine, which undergoes spontaneous oligomerization at relatively low temperatures to form an oligomeric surfactant. Kinetic regularities of the spontaneous oligomerization process of 2-bromomethyloxirane with 1,3-diphenylguanidine at different molar ratios are presented. The effects of the nature of solvents on the conversion of the oligomeric surfactant are also studied. To clarify the reaction of 2-bromomethyloxirane with 1,3-diphenylguanidine, PMR spectra of the initial and final products were recorded, elemental analysis was performed, and UV spectra of the oligomers were recorded.
1. K.Sashidhara, A.Kumar, K.Bhaskara Rao, V.Kushwaha, K.Saxena, P.Murthy. In vitro and in vivo antifilarial activity evaluation of 3,6- epoxy [1,5] dioxins: A new class of antifilarial agents. Bioorganic & Medicinal Chemistry Letters. -2012. №22. -P. 1527-1532.
2. G.N.Merrill. The gas-phase reactivity of epichlorohydrin with hydroxide. Journal Phys. Org. Chem. -2004. №17. -P. 241-248.
3. Каркозов В.Ф. Кинетика взаимодействия дицианамида с эпихлоргидрином // Хим.технол. свойства и применение пластмасс: Сб.науч.тр. -Ленинград. -1981 - С. 53-58.
4. Николаев А.Ф., Каркозов В.Г., Морозов А.Г. Кинетика взаимодействия дицианамида с эпихлоргидрином // Журн.прикл.химии. - Ленинград, 1980. - №5. - С.1799-1801.
5. A.I.Ismailov, N.Edgorov, N.S.Amirkulov. Synthesis and study of the properties of oligomeric surfactants based on epichlorohydrin with nitrogen- and silicon-containing furan compounds // Republic. scientific-practical conf. “Current state and prospects for the development of colloidal chemistry and nanochemistry in Uzbekistan”. -2014. -Tashkent. -P. 126-127.
6. Фозилов С.Ф, Мавлонов Б.А., Ериев О.М. О флоккулирующем действии ионогенных полимеров на основе продуктов взаимодействия эпихлоргидрина с бензоксазолинонами // Узб.хим.журн. -Ташкент. -1997. - №2. - С.45-47.
7. С.Ф.Фозилов, Н.У.Шарипова, Г.Н.Султонов. Исследование самопроизвольной полимеризации эпихлоргидрина с бензоксазолинонами и альфа-аминокислотами // Молодой ученый. -2014. -№6(65). -С.62-64.
8. M.Izadi, H.Mardani, H.Roghani-Mamaqani, M.Salami-Kalajahi, K.Khezri. Hyperbranched Poly(amidoamine)-Grafted Graphene Oxide as a Multifunctional Curing Agent for Epoxy-Terminated Polyurethane Composites // Chemistry Select. -2021. №6. -P. 2692-2699.
9. V.V.Kireev, Y.V.Bilichenko, R.S.Borisov, J.Mu, D.A.Kuznetsov, A.V.Eroshenko, S.N.Filatov, I.S.Sirotin. Synthesis of Bisphenol A Based Phosphazene-Containing Epoxy Resin with Reduced Viscosity // Polymers (Basel). -2019.
10. D.S.McGuinness. Olefin oligomerizatoin via metallacycles: dimerization, trimerization, tetramerization, and beyond // Chem. Rev. -2011. №3. -P. 2321-2341.
11. Levanova E.P., Vilms A.I., Bezborodov V.A., Babenko I.A., Sosnovskaya N.G., Istomina N.V., Albanov A.I., Russavskaya N.V., Rozentsveig I.B. Synthesis of poly-dentate chalcogen-containing ligands using the system hydrazine hydrate-base // Russ. J. Gen. Chem. -2017. №3. -P. 396-401.
12. Б.А.Мухамедгалиев, Ф.Б.Абдукадиров, Р.И.Исмаилов. Полимерные антипирены // - Ташкент, ТАСИ, -2022.
13. Исмаилов Р.И., Азизов Т.А., Хасанов Б.Б., Усманов М.Х. Изучение механизма синтеза олигомерного антипирена на основе 3-хлор-2-оксипропана с 2,4,6-триамино-1,3,5-триазином // Проблемы текстиля. -2010. -№1. -С.45-49.
14. R.I.Ismailov, A.Kh.Abdukakhkhorov, A.I.Ismailov, O.Kh.Khasanov. Study of kinetic regularities of oligomerization of epiodhydrine with N, N'-diphenylguanidine // Technical science and innovation. -Тashkent. -2022. -№1. -P. 14-21.
15. R.I.Ismailov. Synthesis and Mechanism of the Preparation of Polymeric Cationic Surface-Active Substances // International journal of chemical and physical sciences. -2015. -№2. -Р.93-98.
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