СИНТЕЗ МЕТАЛЛОКОМПЛЕКСОВ ДВУХВАЛЕНТНОГО НИКЕЛЯ СО СМЕШАННЫМИ ЛИГАНДАМИ (НАФТАЛИН-1,5-ДИСУЛЬФОКИСЛОТА)
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В данной статье синтезировано тетра аква (1,2-диаминоэтан) никель (II) гидрат нафталин-1,5-дисульфоната
(С 2 H 16 N 2 NiO 4 ) 2+ ·(C 10 H 6 O 6 S 2 ) 2- ·2(H 2 O) комплексное соединение. Предложены структурные формулы и свойства
синтезированного комплекса на основании по результатам ИК спектроскопии, рентгеноструктурного анализа (РСА),
термического анализа. Депозитарные статьи № 2212513 также получены из базы данных SSDS.
1. Mirziyoyev SH.M., O‘zbekiston Respublikasi Prezidentining qarori, 25.10.2018 yildagi PQ-3983-son.
2. Malla R.G., Nagender P., Naresh K.R., Ahn, J.H., Pranay K.K., Kanugula A. K.R., Narsaiah B., Studies on Synthesis of
Novel Triazole Tagged Pyrazole Fused Naphthalene 5-Thiazine-5,5-dioxide Derivatives, Their Antimicrobial, and
Antioxidant Activity. Journal of Heterocyclic Chemistry, (2014). 51(S1), E42–E49. doi:10.1002/jhet.2013
(https://doi.org/10.1002/jhet.2013)
3. Nanjo M., Goto M., Nakashima Y., Synthesis and structure of hypercoordinated germanate complexes with naphthalene-
2,3-dialkoxide ligands. Inorganica Chimica Acta, (2021). 528, 120608. doi:10.1016/j.ica.2021.120608
(https://doi.org/10.1016/j.ica.2021.120608)
4. Abbaspour S., Keivanloo A., Bakherad M., Sepehri S., Salophen copper(II) complex-assisted click reactions for fast
synthesis of 1,2,3-triazoles based on 1,4-naphthoquinone scaffold, anti-bacterial evaluation and molecular docking studies.
Chemistry & Biodiversity. (2018). doi:10.1002/cbdv.201800410 (https://doi.org/10.1002/cbdv.201800410)
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Half-Sandwich Complexes by Naphthalene Displacement. Australian Journal of Chemistry, (2018). 71(4), 289.
doi:10.1071/CH18024 (https://doi.org/10.1071/CH18024)
6. Kamolov S., Babaev B., Ibragimov A., Yakubov Y., Abdullaev A., Ibragimov B., Ashurov J., Synthesis, structure and
Hirshfeld surface analysis of diaquadinitratobis(4-nitroaniline)copper(II) Research communications 2022 yil noyabr IUCr
maʼlumotlari 78(12) DOI: 10.1107/S2056989022010404
7. Mehmet T., Salahattin S., Synthesis and characterization of copper(II), nickel(II) and cobalt (II) complexes with azo-
bonded Schiff base ligands// Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry (2005) DOI
: 10.1081/SIM-200037841
8. Cho J., Hwa J.J., Jin Sh.H., Sik M.K., Synthesis, structure and photoluminescence properties of naphthalene-based chiral
zinc(II) complexes. (2020) Polyhedron, 114643. doi:10.1016/j.poly.2020.114643 (https://doi. org/10.1016/j.poly.
2020.114643)
9. Prasad K.S., Pillai R.R., Armaković S., Armaković S.J., Photophysical properties and theoretical investigations of newly
synthesized pyrene-naphthalene based Schiff base ligand and its copper(II) complexes. Inorganica Chimica Acta. (2018).
doi:10.1016/j.ica.2018.11.045 (https://doi.org/10.1016/j.ica. 2018.11.045)
10. Tunçel M., Serin S., Synthesis and Characterization of Copper (II), Nickel (II) and Cobalt (II) Complexes with Azo‐
Linked Schiff Base Ligands. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, (2005).
35(3), 203–212. doi:10.1081/SIM-200037841 (https://doi.org/10.10 81/SIM-200037841)
11. Brett R.M., Dadsetan M., Baltrusaitis J., Knight A.M., Ruesink T., Lazcano E.A., Yaszemski M.J., The development of
electrically conductive polycaprolactone fumarate–polypyrrole composite materials for nerve regeneration. Biomaterials,
(2010). 31(23), 5916–5926.doi:10.1016/j. biomaterials. 2010.04.012 (https://doi.org/10.1016/j.biomaterials.2010.04.012)
12. Fatmah M.A., Thoraya A.F., Marwa F.H., Hoda A.E., Copper (II) complexes based on 1,3,4-thiadiazolethiosemicarbazone
NNS donor ligands: synthesis, molecular structure, DNA binding and in silico molecular docking approach // Received 31
Oct 2020, Accepted 21 Nov 2021, Published online: 07 Dec 2021 https://doi.org/10.1080/24701556.2021.2011319
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