ANTRATSENNI NITRAT KISLOTA YORDAMIDA ANTRAXINONGACHA OKSIDLASH
##submission.downloads##
Ushbu ishda antrasenni turli oksidlovchilar yordamida oksidlab, 9,10-antraxinon olish jarayoni o‘rganildi. Tadqiqotning dolzarbligi antraxinonning bo‘yoqlar sanoatidagi muhim oraliq mahsulot sifatidagi ahamiyati bilan belgilanadi. Metodologik yondashuv sifatida turli oksidlovchilar ishtirokida reaksiyalar olib borilib, ularning samaradorligi tahlil qilindi. Natijada kislorod ishtirokida 56% azot kislotasi bilan oksidlash orqali, yuqori unumda antraxinon olish imkoniyati ko‘rsatildi. Tadqiqot natijalari asosida antrasenning markaziy 9,10-holatidagi vodorodi faollikka ega ekanligi aniqlandi.
1. Шадиева, Г.; Нурмонов, С.; Кадиров, О. Выделение антрацена из вторичного продукта и его использование в синтезе ионообменных материалов. В кн.: Kimyo fanining muammolari, sanoat sohalariga tatbiqi va yashil texnologiyalar mavzusidagi xalqaro anjuman materiallari, Toshkent, O‘zbekiston, 18–19 aprel 2025 yil; ISNB 978-9910-695-76-6; сс. 1227–1229.
2. Шадиева Г.К. Антраценни турли оксидловчилар ёрдамида 9,10-антрахинонгача оксидлаш усуллари. “Келажакка кимё билан интиламиз” мавзусидаги илмий-амалий анжуман материаллари. Тошкент, Ўзбекистон, 22-23 май 2025 йил; бб.72-74
3. Brown GS, Barton LL, Thomson BM. Permanganate oxidation of sorbed polycyclic aromatic hydrocarbons. Waste Manag. 2003;23(8):737-40.
4. Bonfranceschi, A.; Briand, L. E.; Thomas, H. J. Selective Oxidation of Anthracene to 9,10-Anthraquinone over Silica Supported Vanadium Catalyst. React. Kinet. Catal. Lett. 2002, 77 (1), 59–64.
5. Sharma, N.; Jung, J.; Lee, Y.-M.; Seo, M. S.; Nam, W.; Fukuzumi, S. Multi-Electron Oxidation of Anthracene Derivatives by Nonheme Manganese (IV)-Oxo Complexes. Angew. Chem. Int. Ed. 2010, 49 (28), 5164–5167.
6. Krumova, K.; Cosa, G. Chapter 1: Overview of reactive oxygen species. In Singlet Oxygen: Applications in Biosciences and Nanosciences, 1st ed.; RSC: London, UK, 2016; pp. 1–21.
7. Kumar, R.; Singh, S.; Singh, A. “Electrochemical Behavior of Anthraquinone Derivatives in Energy Storage Applications.” ACS Appl. Energy Mater. 2019, 2 (7), 4727–4736.
8. Sharma, V.; Kumar, A.; Rana, S. “Anthraquinone Functionalized Materials for Dye-Sensitized Solar Cells.” J. Phys. Chem. C 2018, 122 (14), 7798–7808.
9. Routoula, E.; Patwardhan, S. V. Degradation of Anthraquinone Dyes from Effluents: A Review Focusing on Enzymatic Dye Degradation with Industrial Potential. ACS Sustainable Chem. Eng. 2020, 8 (12), 4813–4830.
10. Díaz-Uribe C., Méndez-Romero D., Reyes-Santiago J., et al. Physical-Chemical Study of Anthracene Selective Oxidation by Hydroxyl Radicals // International Journal of Molecular Sciences. – 2020. – Vol.21, №2. – P.345-356.
Mulkiiyat (c) 2025 «O‘zMU XABARLARI»
Ushbu ish quyidagi litsenziya asosida ruxsatlangan Kreativ Commons Attribution-NonCommercial-ShareAlike 4.0 International litsenziyasi asosida bu ish ruxsatlangan..
.jpg)
.png)
