EFFECTS OF MONOLAYER ADSORPTION OF CS ATOMS ON THE ELECTRONIC STRUCTURE, EMISSION AND OPTICAL PROPERTIES OF GAP (111)
Using the methods of ultraviolet photoelectron spectroscopy, light absorption spectroscopy and true secondary electrons, the effect of deposition of Cs atoms with a thickness of 1 monolayer on the density of states of electrons in the valence and conduction bands, the parameters of the energy band, and the quantum yield of photoelectrons were studied. It was found that when cesium is deposited on the surface of GaP (111) single crystals with a thickness of 1 monolayer, the value of Eg and the position of the maxima of the density of states of valence electrons remain virtually unchanged, the work function of photoelectrons decreases to 1.94 eV, and the quantum yield of photoelectrons increases by 5 or more times. Key words: Surface, thickness, work function, monolayer, structure, single crystal, deposition
1. Mudar Ahmed Abdulsattar, Bahjat B. Kadhim and Huda M. Jawad. Electronic, Structural and Vibrational Properties of GaP Diamondoids and Nanocrystals: A Density Functional Theory Study. Nanomater Nanotechnol, 2015, 5:15 | doi: 10.5772/60577.
2. Lorenz M R, Pettit G D, Taylor R C (1968) Band Gap of Gallium Phosyhide from 0 to 900K and Light Emission from Diodes at High Temperatures. Phys. Rev. 171:876.
3. Assali S, Zardo I, Plissard S, Kriegner D, Verheijen M A, Bauer G, Meijerink A, Belabbes A, Bechstedt F, Haverkort J E M, Bakkers E P A M (2013) Direct Band Gap Wurtzite Gallium Phosphide Nanowires. Nano Lett. 13:1559.
4. NSM Archive, Physical Properties of Semiconduc‐ tors, Available: http://www.ioffe.ru/SVA/NSM/ Semicond/. Accessed 2014 June 1.
5. Fedorchenko I. V., Kushkov A. R., Gaev D. S., et al., Growth method for AIIIBV and AIVBVI heterostructures, J. Cryst. Growth. 483 (1 February) (2018) 245–250.
6. Spirina A. A., Nastovjak A. G., Usenkov S.V., Shvarts N. L., Lattice Monte Carlo model of Langmuir evaporation of AIIIBV semiconductors, J. Comput. Technol. 23 (6) (2018) 81–94.
7. Alexander S. Gudovskikh,a) Ivan A. Morozov, Alexander V. Uvarov, Dmitriy A. Kudryashov, Ekaterina V. Nikitina, and Anton S. Bukatin. Low temperature plasma enhanced deposition of GaP films on Si substrate. J. Vac. Sci. Technol. A, Vol. 36, No. 2, Mar/Apr 2018
8. S. M. Sze, Physics of Semiconductor Devices, 2nd ed. (Wiley, New York, 1981).
9. H. Wagner, T. Ohrdes, A. Dastgheib-Shirazi, B. Puthen Veettil, D. K€onig, and P. P. Altermatt, J. Appl. Phys. 115, 044508 (2014).
10. 4 M. Feifel, T. Rachow, J. Benick, and J. Ohlmann, IEEE J. Photovoltaics 6, 384 (2016). 5 M. Sadeghi and S. Wang, J. Cryst. Growth 227–228, 279 (2001).
11. M. S. Sobolev, A. A. Lazarenko, E. V. Nikitina, E. V. Pirogov, A. S. Gudovskikh, and A. Yu. Egorov, Semicond. 49, 559 (2015).
12. J. F. Geisz, J. M. Olson, D. J. Friedman, K. M. Jones, R. C. Reedy, and M. J. Romero, 31th IEEE PVSC (2005), p. 695.
13. A. S. Gudovskikh, K. S. Zelentsov, A. I. Baranov, D. A. Kudryashov, I. A. Morozov, E. V. Nikitina, and J.-P. Kleider, Energy Procedia 102, 56 (2016).
14. B.E. Umirzakov, I.R. Bekpulatov, I.Kh. Turapov, B.D. Igamov. Effect of Deposition of Submonolayer Cs Coatings on the Density of Electronic States and Energy Band Parameters of CoSi2/Si(111). J. NANO- ELECTRON. PHYS. 14, 02026 (2022)
15. G. M. Shirinov, S. B. Donaev, B. Y. Umirzakov, V. V. Loboda. Emission, optical and electrical properties of GaInP/GaP nanofilms. St. Petersburg State Polytechnical University Journal. Physics and Mathematics. 2023. Vol. 16. No. 2. DOI: https://doi.org/10.18721/JPM.16208.
16. Umirzakov B.E., Pugacheva T.S., Tashatov A.T., Tashmukhamedova D.A. Electronic structure and optical properties of CaF2 films under low energy Ba+ ion-implantation combined with annealing. // Nuclear instruments & Methods in physics research section b-beam interactions with materials and atoms. DOI: 10.1016/S0168-583X(99)01151-9 2000, Vol. 166, № 2, Page 572-576.
17. Donaev S. B., Tashatov A. K., Umirzakov B. E. Effect of Ar+- Ion Bombardment on the Composition and Structure of the Surface of CoSi2/Si(111) Nanofilms. // Journal of surface investigation. DOI: 10.1134/S1027451015020263. 2015, Vol. 9, № 2, Page 406-409.
18. Кораблев В.В., Кудинов Ю.А., Сысоев С.Н. Проявление зонной структуры твердого тела в спектрах вторичных электронов с угловым разрешением // Физика твердого тела, 1986, том 28, выпуск 9, с. 2648-2654.
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