Cu(II) ATSETATNING 2-PROPIONILAMINOBENZIMIDAZOL BILAN KOMPLEKSINI SINTEZI VA TADQIQOTI
##submission.downloads##
Tadqiqotda mis(II) atsetat va 2-propionilaminobenzimidazol (L) ligandi asosida yangi [CuL2(CH3COO)2]·H2O kompleksi sintez
qilindi. Kompleks tuzilishi element tahlili, monokristall RST va Hirshfeld sirt tahlili yordamida oʻrganildi. Kristallografik
ma’lumotlarga koʻra, Cu(II) kationi ligandning endotsiklik azot va gidroksil kislorodi atomlari orqali bidentat usulda
koordinatsiyalangan. Kompleksning koordinatsion poliedri kvadrat-bipiramida geometriyaga ega boʻlib, Yan–Teller effekti
hisobiga tetragonal choʻzilishga uchraganligi tasdiqlandi.
1. Mohapatra T.R., Ganguly S. The recent development of benzimidazole derivative as a promising pharmacological scaffold
// Journal of the Indian Chemical Society. - 2024. - Vol. 101, № 9. - Art. 101237.
2. Autade L., Manikpuriya S., Sanap G. Benzimidazole Derivatives and Its Biological Importance // Journal of Scientific and
Innovative Research. - 2023. - Vol. 12, № 4. - P. 89–91. DOI: 10.31254/jsir.2023.12404.
3. Spackman P.R., Turner M.J., McKinnon J.J., Wolff S.K., Grimwood D.J., Jayatilaka D., Spackman M.A. CrystalExplorer: a
program for Hirshfeld surface analysis, visualization and quantitative analysis of molecular crystals // Journal of Applied
Crystallography. - 2021. - Vol. 54, № 3. - P. 1006-1011.
4. Cui J.W., Zhao Y.Q., Hao Z.C., Cui G.H. Synthesis, structural characterization, and Hirshfeld surface analysis of three
cocrystals based on flexible bis(benzimidazole) derivatives with aromatic carboxylic acids // Research on Chemical
Intermediates. - 2018. - Vol. 44, № 1. - P. 721–738.
5. Abu-Dief A.M., El-Khatib R.M., El-Dabea T., Feizi-Dehnayebi M., Barnawi I.O., Alsehli A.H. et al. Design, preparation,
physicochemical characterization, structural conformational, biological evaluation, and DNA interaction for some new
benzimidazole complexes // Applied Organometallic Chemistry. - 2024. - Vol. 38, № 3. - Art. e7358.
Mulkiiyat (c) 2026 «O‘zMU XABARLARI»
Ushbu ish quyidagi litsenziya asosida ruxsatlangan Kreativ Commons Attribution-NonCommercial-ShareAlike 4.0 International litsenziyasi asosida bu ish ruxsatlangan..
.jpg)
.png)
