BENZALDEGID VA UNING AYRIM HOSILALARINI 4-ETINIL-p-AMINOFENILATSETILEN ISHTIROKIDA ALKINILLASH
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Ushbu ishda ilk bor Rh2(AcO)4·2H2O/Et2O/Et3N kompleks katalitik sistemasi yordamida benzaldegid va uning ayrim gomologlarining 4-etinil-p-aminofenilatsetilen bilan reaksiyalari asosida molekulasida turli xil o‘rinbosarlar saqlagan atsetilen spirtlarini sintez qilish usuli ishlab chiqilgan. Tanlangan aldegidlar molekulasidagi radikallar tabiatining mahsulot unumi va reaksiya borishiga taʼsiri aniqlangan. Kompleks katalitik sistemaning reaksiya selektivligi, faollanish energiyasi va termodinamikasiga ta’siri o‘rganilgan, jarayonning ximizmi va reaksiya mexanizmlari taklif etilgan. Sintez qilingan birikmalarning hususiy konstantalari, tuzilishi, tarkibi va kvant-kimyoviy hisoblashlari zamonaviy fizik-kimyoviy tadqiqot usullari yordamida isbotlangan.
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