YANGI KATALITIK SISTEMALARDA ATSETILEN SPIRTLARIDAN DIINDIOLLAR SINTEZ QILISH JARAYONI
"Maqola"
Ushbu ishda katalizator sifatida mis (I) xlorid, ligand sifatida N,N,Nˊ,Nˊ- tetrametiletilendiamin, oksidlovchi agent tetraxlorometan va erituvchi metanol yordamida molekulasida alifatik, alisiklik, aromatik ва geterosiklik saqlagan terminal atsetilen spirtlarining oksidlanish bilan boradigan gomolitik birikish reaksiyasi asosida diatsetilen diollari sintezi tadqiq qilingan. Terminal atsetilen spirtlarining dimerlanish jarayonining eng muqobil sharoitlari aniqlangan va reaksiya kinetikasi tahlil qilingan. Sintez qilingan diatsetilen diollari identifikatsiyalangan, ularning xususiy konstantalari, tuzilishi, tozaligi va tarkibi zamonaviy fizik-kimyoviy tadqiqot usullari yordamida isbotlangan
References
Krzysztof Kuciński, AlicjaŁuczak, Aliaksei Mankouski, Grzegorz Hreczycho Base-catalyzed addition of silylacetylenes to ketones: a route to protected tertiary propargyl alcohols // Organic Chemistry Frontiers, 2023. Volume 10, Issue 11, Pages 2752-2759.
S.Jiang, S.Du, R.Yang, F.Jin, Z.-Z. Zhou, W.-F. Tian, X.-R.Song, Q.Xiao Brønsted Acid Promoted Sulfonylation of Propargylic Alcohols: Synthesis of Triaryl Allenyl Sulfones under Mild Conditions // European Journal of Orgnic Chemistry 2023. p.e202201377.
A.R.Pandey, D.K.Tiwari, A.Prakhar, D.P.Mishra, S.K.Sharma A review towards synthesis of heterocycles using propargyl alcohols and propargyl amines // Monatshefte fur Chemie, 2022. Volume 153, pp. 383-407.
Qi Xie, Changhong Wang Polyacetylenes in herbal medicine: A comprehensive review of its occurrence, pharmacology, toxicology, and pharmacokinetics (2014–2021) // Phytochemistry, 2022. Volume 201, pp. 113-288.
Fatma M. Abdel Bar, Amira Mira, Ahmed I. Foudah, Manal A. Alossaimi, Shatha F. Alkanhal, Alanoud M. Aldaej and Mai H. ElNaggar In Vitro and In Silico Investigation of Polyacetylenes from Launaea capitata (Spreng.) Dandy as Potential COX-2, 5-LOX, and BchE Inhibitors // Molecules, 2023. Volume 28, Issue 8, pp. 3526.
Tirkasheva S.I., Ziyadullaev O.E., Samatov S.B., Buriyev F.X., Ikramov A. Dimerization of some terminal acetylene alcohols / VI North Caucasus Organic Chemistry Symposium, Stovropol (Russia), 2022. p. 133. 7. Rabia Akhtar, Ameer Fawad Zahoor Transition metal catalyzed Glaser and GlaserHay coupling reactions: Scope, classical/green methodologies and synthetic applications // Synthetic Communications, 2020. Volume 50, Issue 22, pp. 3337-3368.
Housecroft Catherine E., Alan G. Sharpe Inorganic Chemistry: – Harlow: Pearson Education, 2008. pp. 737-738.
Copyright (c) 2024 O‘zMU xabarlari
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.