YANGI KATALITIK SISTEMALARDA ATSETILEN SPIRTLARIDAN DIINDIOLLAR SINTEZ QILISH JARAYONI

  • Odiljon ZIYADULLAYEV Chirchiq davlat pedagogika universiteti ilmiy ishlar va innovatsiyalar bo‘yicha prorektori, kimyo fanlari doktori
  • Go‘zal OTAMUXAMEDOVA Chirchiq davlat pedagogika universiteti, ilmiy - tadqiqotlar, innovatsiyalar va ilmiy pedagog kadrlar tayyorlash bo‘limi boshlig‘i, kimyo fanlari bo‘yicha falsafa doktori
  • Sarvinoz TIRKASHEVA Jizzax davlat pedagogika universiteti, Tabiiy fanlar fakulteti kimyo va uni o‘qitish metodikasi kafedrsi o‘qituvchisi, kimyo fanlari bo‘yicha falsafa doktori
  • Valentin NENAYDENKO Moskva davlat universiteti Organik kimyo kafedra mudiri, kimyo fanlari doktori
  • Saida ABDURAXMANOVA O‘zbekiston Milliy Universiteti, Kimyo fakulteti, umumiy va neft-gaz kimyo kafedrasi katta o‘qituvchisi, kimyo fanlari bo‘yicha falsafa doktori
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"Kalit so‘zlar" : Terminal atsetilen spirtlari, diatsetilen diollari, dimerlanish, katalitik sistema, reaksiya mexanizmi, mahsulot unumi.

"Maqola"

Ushbu ishda katalizator sifatida mis (I) xlorid, ligand sifatida N,N,Nˊ,Nˊ- tetrametiletilendiamin, oksidlovchi agent tetraxlorometan va erituvchi metanol yordamida molekulasida alifatik, alisiklik, aromatik ва geterosiklik saqlagan terminal atsetilen spirtlarining oksidlanish bilan boradigan gomolitik birikish reaksiyasi asosida diatsetilen diollari sintezi tadqiq qilingan. Terminal atsetilen spirtlarining dimerlanish jarayonining eng muqobil sharoitlari aniqlangan va reaksiya kinetikasi tahlil qilingan. Sintez qilingan diatsetilen diollari identifikatsiyalangan, ularning xususiy konstantalari, tuzilishi, tozaligi va tarkibi zamonaviy fizik-kimyoviy tadqiqot usullari yordamida isbotlangan

References

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S.Jiang, S.Du, R.Yang, F.Jin, Z.-Z. Zhou, W.-F. Tian, X.-R.Song, Q.Xiao Brønsted Acid Promoted Sulfonylation of Propargylic Alcohols: Synthesis of Triaryl Allenyl Sulfones under Mild Conditions // European Journal of Orgnic Chemistry 2023. p.e202201377.

A.R.Pandey, D.K.Tiwari, A.Prakhar, D.P.Mishra, S.K.Sharma A review towards synthesis of heterocycles using propargyl alcohols and propargyl amines // Monatshefte fur Chemie, 2022. Volume 153, pp. 383-407.

Qi Xie, Changhong Wang Polyacetylenes in herbal medicine: A comprehensive review of its occurrence, pharmacology, toxicology, and pharmacokinetics (2014–2021) // Phytochemistry, 2022. Volume 201, pp. 113-288.

Fatma M. Abdel Bar, Amira Mira, Ahmed I. Foudah, Manal A. Alossaimi, Shatha F. Alkanhal, Alanoud M. Aldaej and Mai H. ElNaggar In Vitro and In Silico Investigation of Polyacetylenes from Launaea capitata (Spreng.) Dandy as Potential COX-2, 5-LOX, and BchE Inhibitors // Molecules, 2023. Volume 28, Issue 8, pp. 3526.

Tirkasheva S.I., Ziyadullaev O.E., Samatov S.B., Buriyev F.X., Ikramov A. Dimerization of some terminal acetylene alcohols / VI North Caucasus Organic Chemistry Symposium, Stovropol (Russia), 2022. p. 133. 7. Rabia Akhtar, Ameer Fawad Zahoor Transition metal catalyzed Glaser and GlaserHay coupling reactions: Scope, classical/green methodologies and synthetic applications // Synthetic Communications, 2020. Volume 50, Issue 22, pp. 3337-3368.

Housecroft Catherine E., Alan G. Sharpe Inorganic Chemistry: – Harlow: Pearson Education, 2008. pp. 737-738.

Nashr qilingan
2024-11-29